Precautionary statements for substances and mixtures

 

According to Regulation (EC) No 1272/2008 a.k.a "CLP", a precautionary statement, or "P statement" is:

a phrase that describes recommended measure(s) to minimise or prevent adverse effects resulting from exposure to a hazardous substance or mixture due to its use or disposal.

Here is a list of all the P statements, as described in the CLP Regulation, categorised.

 

General precautionary statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.

Prevention precautionary statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. [As modified by IV ATP]
P211 Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/…/combustible materials.
P221 Take any precaution to avoid mixing with combustibles.
P222 Do not allow contact with air.
P223 Do not allow contact with water. [As modified by IV ATP]
P230 Keep wetted with …
P233 Keep container tightly closed.
P234 Keep only in original container.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/light/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P244 Keep valves and fittings free from oil and grease.
P250 Do not subject to grinding/shock/…/friction.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fumes/gas/mist/vapours/spray.
P261 Avoid breathing dust/fumes/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P263 Avoid contact during pregnancy/while nursing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P282 Wear cold insulating gloves/face shield/eye protection.
P283 Wear fire/flame resistant/retardant clothing.
P284 [In case of inadequate ventilation] wear respiratory protection.
P231
+ P232
Handle under inert gas. Protect from moisture
P235
+ P410
Keep cool. Protect from sunlight

Response precautionary statements

P310 Immediately call a POISON CENTER/doctor
P311 Call a POISON CENTER/ doctor
P312 Call a POISON CENTER/ doctor/…/if you feel unwell.
P314 Get Medical advice/attention if you feel unwell.
P315 Get immediate medical advice/attention.
P320 Specific treatment is urgent (see … on this label).
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P336 Thaw frosted parts with lukewarm water. Do not rub affected areas.
P363 Wash contaminated clothing before reuse.
P372 Explosion risk in case of fire.
P373 DO NOT fight fire when fire reaches explosives.
P374 Fight fire with normal precautions from a reasonable distance.
P377 Leaking gas fire – do not extinguish unless leak can be stopped safely.
P380 Evacuate area.
P381 Eliminate all ignition sources if safe to do so.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage.
P301
+ P310
IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
P301
+ P312
IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell.
P301
+ P330
+ P331
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302
+ P334
IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302
+ P352
IF ON SKIN: Wash with plenty of water/…
P303
+ P361
+ P353
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304
+ P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305
+ P351
+ P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P306
+ P360
IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P308
+ P311
IF exposed or concerned: Call a POISON CENTER/ doctor/…
P308
+ P313
IF exposed: Call a POISON CENTER or doctor/physician.
P332
+ P313
If skin irritation occurs: Get medical advice/attention.
P333
+ P313
If skin irritation or a rash occurs: Get medical advice/attention.
P335
+ P334
Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337
+ P313
If eye irritation persists get medical advice/attention.
P342
+ P311
If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…
P361
+ P364
Take off immediately all contaminated clothing and wash it before reuse.
P362
+ P364
Take off contaminated clothing and wash it before reuse.
P370
+ P376
In case of fire: Stop leak if safe to do so
P370
+ P378
In case of fire: Use … to extinguish.
P370
+ P380
In case of fire: Evacuate area.
P370
+ P380
+ P375
In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371
+ P380
+ P375
In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

Storage precautionary statements

P401 Store …
P403 Store in a well ventilated place.
P405 Store locked up.
P406 Store in a corrosive resistant/… container with a resistant inner liner.
P407 Maintain air gap between stacks/pallets.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding … °C/… °F.
P420 Store away from other materials.
P422 Store contents under …
P402
+ P404
Store in a dry place. Store in a closed container.
P403
+ P233
Store in a well ventilated place. Keep container tightly closed.
P403
+ P235
Store in a well ventilated place. Keep cool.
P410
+ P403
Protect from sunlight. Store in a well-ventilated place.
P410
+ P412
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P411
+ P235
Store at temperatures not exceeding … °C/… °F. Keep cool.
P501 Dispose of contents/container to …

Disposal precautionary statements

P501 Dispose of contents/container to …
P502 Refer to manufacturer/supplier for information on recovery/recycling.